Electrogeneration of H2o2 Through Carbon-Based Ink on Al Foam for Electro-Fenton Treatment of Micropollutants in Water

In the present work, the catalytic efficiency of inks based on different carbon materials, namely activated carbon (AC), carbon graphite (CG), and carbon black (CB) was investigated for the oxygen reduction reaction (ORR). Additionally, we explored the feasibility of using this ink as a coating for an Aluminum foam (Al<inf>foam</inf>) cathode in an electrochemical cell. The goal was to utilize this setup to produce hydrogen peroxide (H<inf>2</inf>O<inf>2</inf>) in the electro-Fenton (EF) process, targeting for treating water contaminated with contaminants of emerging concern (CECs). Among the materials investigated, all of them exhibited the ability to facilitate the ORR. However, AC proved to be the most suitable material due to its optimal balance between physical and electrocatalytic properties, thus enabling the formation of H<inf>2</inf>O<inf>2</inf>. When the different inks were applied to the surface of aluminum foam, it was observed that only the ink based on carbon black CB achieved a homogeneous distribution with the same ink quantity. As a result, it was observed that the Alfoam/CB electrode exhibited the highest H<inf>2</inf>O<inf>2</inf> generation capacity, producing 45.6 mg L-1, followed by electro-generation of 5.1 mg L-1 using Alfoam/AC and 11 mg L-1 using Alfoam/CG. Furthermore, the application of Alfoam/CB in EF processes allowed for the almost complete degradation of 15 emerging contaminants of concern (CECs) present in secondary effluent. The innovative outcome of this study positions the developed technology as a promising and effective alternative for the treatment of water contaminated with CECs, demonstrating significant potential for industrial-scale application. © 2023